Further studies in the elution of copper and neodymium from a cation-exchange resin with ammonia-ethylenediaminetetraacetic acid solutions

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1960-02-01
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Matson, Lyle
Spedding, F.
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Ames National Laboratory

Ames National Laboratory is a government-owned, contractor-operated national laboratory of the U.S. Department of Energy (DOE), operated by and located on the campus of Iowa State University in Ames, Iowa.

For more than 70 years, the Ames National Laboratory has successfully partnered with Iowa State University, and is unique among the 17 DOE laboratories in that it is physically located on the campus of a major research university. Many of the scientists and administrators at the Laboratory also hold faculty positions at the University and the Laboratory has access to both undergraduate and graduate student talent.

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Abstract

It was shown that flat elution curves were maintained with constant length rare-earth bands using either copper-ammonium- hydrogen or copper-hydrogen retaining beds. However, when the copper-hydrogen retaining band was used, some precipitation occurred at the lower boundary region or the rare-earth band. When the copper-ammonium-hydrogen band was used, a longer time was required to achieve equilibrium in this bend. When a narrow copper-ammonium-hydrogen bend was used, between the rare-earth and the copper-hydrogen bed, the precipitation was prevented and the "tlat" equilibrium type elution curves were obtained. It was demonstrated that when a final retaining bed of the proper composition is used with a given eluant, then the interposed band and the rare-earth band maintain a. constant length. In addition, it was demonstrated that, when the final retaining bed was not compatible with the eluant, then the flat type elution curves were maintained with the interposed band growing in length and the rare-earth band remaining constant in length.

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