The objective of this research was to investigate the physical/chemical and water flow characteristics of various previous concrete mixes made of different concrete materials and their effectiveness in attenuating water pollution. Four pervious concrete mixes were prepared with Portland cement and with 15% cementitious materials (slag, limestone powder, and fly ash) as a Portland cement replacement. All four pervious concrete mixtures had acceptable workability. The unit weight of the fresh pervious concrete mixtures ranged from 115.9 lb/yd3 to 119.6 lb/yd3 , while the 28 day compressive strength of the pervious concrete mixes ranged from 1858 psi (mix with 15% slag) to 2285 psi (pure cement mix). The compressive strength generally increased with unit weight and decreased with total porosity (air void ratio). The permeability of the four mixes generally decreased with unit weight and increased with total porosity. The permeability coefficients ranged from 340 in./hr for the pure cement mix to 642 in./hr for the mix with 15% slag. The total porosities of the four pervious concrete mixes ranged from 24.00% (mix with 15% slag) to 31.41% (pure cement mix) as measured by the flatbed scanner test method, while the porosities ranged from 18.93% (mix with 15% slag) to 24.15% (pure cement mix) as measured by the RapidAir method. The total porosities of the four pervious concrete mixes measured by the flatbed scanner method were higher than those measured by the Rapid Air method, but the specific surface areas measured by the flatbed scanner method were all lower than those measured by the Rapid Air method. For the pollution abatement experiments, mixes with fly ash and limestone powder removed about 30% of the input naphthalene concentration, while the mix with slag only removed 0.5% of the influent naphthalene concentration. The water volume balance showed that less than 1% of the water added was retained in the experimental column setup.