Direct Synthesis of the Phenanthroviridone Skeleton Using a Highly Regioselective Nitroquinone Diels–Alder Reaction
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2020-04-28
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Ames National LaboratoryChemistry
Abstract
A variety of nucleophiles react efficiently with in situ generated nitroquinones. The reaction with substituted resorcinols led to the direct synthesis of the phenanthroviridinone and lagumycin skeleton via a highly regioselective Diels–Alder reaction.
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This article is published as Yu, Huangchao, Ellie L. Fought, Theresa L. Windus, and George A. Kraus. "Direct Synthesis of the Phenanthroviridone Skeleton Using a Highly Regioselective Nitroquinone Diels–Alder Reaction." ACS Omega 5, no. 16 (2020): 9311-9315. DOI: 10.1021/acsomega.0c00201. Posted with permission.
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Wed Jan 01 00:00:00 UTC 2020