Hydrogen atom abstraction reactions in organic synthesis. A formal total synthesis of racemic podophyllotoxin
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1992-05-01
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Kraus, George
University Professor Emeritus
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Chemistry
Abstract
The key step in a synthesis of 1 was a tandem photoenolization/Diels-Alder reaction to produce 11. Hydrolysis of the acetal and ester followed by oxidation afforded 15, an advanced intermediate in the Meyers synthesis of 1.
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Reprinted (adapted) with permission from The Journal of Organic Chemistry, 57(10); 2922-2925. Doi: 10.1021/jo00036a030. Copyright 1992 American Chemical Society.
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Wed Jan 01 00:00:00 UTC 1992