Auxetic behavior under electrical loads in an induced ferroelectric phase

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2009-01-30
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Tan, Xiaoli
Jo, Wook
Granzow, T.
Frederick, Joshua
Aulbach, E.
Rodel, J.
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Tan, Xiaoli
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Materials Science and Engineering
Materials engineers create new materials and improve existing materials. Everything is limited by the materials that are used to produce it. Materials engineers understand the relationship between the properties of a material and its internal structure — from the macro level down to the atomic level. The better the materials, the better the end result — it’s as simple as that.
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Abstract

The longitudinal and transverse strains were measured as a function of applied electric fields in a bulk ceramic sample of Pb0.99Nb0.02[(Zr0.57Sn0.43)0.94Ti0.06]0.98O3 at room temperature. Instead of a transverse contraction, a transverse expansion was observed in the electric-field-induced ferroelectric phase after the antiferroelectric-to-ferroelectric phase transition. Therefore, an auxetic behavior was established in monolithic ferroelectric polycrystalline ceramics under electrical loads. The behavior is characterized by a negative strain ratio that is analogous to the Poisson’s ratio. The transverse expansion leads to a large hydrostatic piezoelectric coefficient dh, which suggests new applications of antiferroelectricceramics in piezoelectric devices.

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The following article appeared in Applied Physics Letters 94 (2009): 042909 and may be found at http://dx.doi.org/10.1063/1.3076109.

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Thu Jan 01 00:00:00 UTC 2009
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