Direct observation of the recovery of an antiferroelectric phase during polarization reversal of an induced ferroelectric phase

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2015-04-01
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Guo, Hanzheng
Tan, Xiaoli
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Tan, Xiaoli
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Materials Science and Engineering
Materials engineers create new materials and improve existing materials. Everything is limited by the materials that are used to produce it. Materials engineers understand the relationship between the properties of a material and its internal structure — from the macro level down to the atomic level. The better the materials, the better the end result — it’s as simple as that.
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Abstract

Electric fields are generally known to favor the ferroelectric polar state over the antiferroelectric nonpolar state for their Coulomb interactions with dipoles in the crystal. In this paper, we directly image an electric-fieldassisted ferroelectric-to-antiferroelectric phase transition during polarization reversal of the ferroelectric phase in polycrystalline Pb0.99{Nb0.02[(Zr0.57Sn0.43)0.92Ti0.08]0.98}O3.With the electric-field in situ transmission electron microscopy technique, such an unlikely phenomenon is verified to occur by both domain morphology change and electron-diffraction analysis. The slower kinetics of the phase transition, compared with ferroelectric polarization reversal, is suggested to contribute to this unusual behavior.

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This article is from Physical Review B 91 (2015): 1, doi:10.1103/PhysRevB.91.144104. Posted with permission.

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Thu Jan 01 00:00:00 UTC 2015
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