Agricultural and Biosystems Engineering Publications
Campus Units
Agricultural and Biosystems Engineering, Civil, Construction and Environmental Engineering, Food Science and Human Nutrition, Toxicology
Document Type
Article
Publication Version
Accepted Manuscript
Publication Date
12-2016
Journal or Book Title
TrAC Trends in Analytical Chemistry
Volume
85
Issue
Part A
First Page
111
Last Page
122
Research Focus Area(s)
Land and Water Resources Engineering
DOI
10.1016/j.trac.2016.04.007
Abstract
This study explores the current state-of-the-art progress toward on-site quantification of organic pollutants in soils with solid-phase microextraction (SPME). In spite of many available methods, only few publications report on-site analyses of soil samples by SPME. To date, the only application of SPME for the on-site quantification of organic pollutants in soil has been devoted to trichloroethylene. The problem of matrix effects limiting quantification by external standard calibration is discussed. Efficiencies of available approaches for decreasing and controlling matrix effects are evaluated and compared. SPME from a soil sample headspace with internal standard calibration was identified as one of the promising approaches to achieve fast, simple, precise, and accurate on-site quantification of a wide range of organic pollutants in soil. Cold-fiber SPME has a significant development potential, because it is capable of providing lowest detection limits together with a minimum matrix effect. Perspectives for future development of the field are outlined.
Creative Commons License
This work is licensed under a Creative Commons Attribution-Noncommercial-No Derivative Works 4.0 License.
Copyright Owner
Elsevier B.V.
Copyright Date
2016
Language
en
File Format
application/pdf
Recommended Citation
Kenessov, Bulat; Koziel, Jacek A.; Bakaikina, Nadezhda V.; and Orazbayeva, Dina, "Perspectives and challenges of on-site quantification of organic pollutants in soils using solid-phase microextraction" (2016). Agricultural and Biosystems Engineering Publications. 891.
https://lib.dr.iastate.edu/abe_eng_pubs/891
Figures 1-7
2016-Koziel-PerspectivesChallenges-Suppl_Tables.pdf (28 kB)
Tables 1-2
Included in
Agriculture Commons, Bioresource and Agricultural Engineering Commons, Environmental Health Commons, Toxicology Commons
Comments
This is a manuscript of an article published as Kenessov, Bulat, Jacek A. Koziel, Nadezhda V. Bakaikina, and Dina Orazbayeva. "Perspectives and challenges of on-site quantification of organic pollutants in soils using solid-phase microextraction." TrAC Trends in Analytical Chemistry 85 (2016): 111-122. DOI: 10.1016/j.trac.2016.04.007. Posted with permission.