Ethanol purification with ozonation, activated carbon adsorption, and gas stripping

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2015-09-04
Authors
Cai, Lingshuang
Rice, Somchai
van Leeuwen, Johannes
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Rice, Somchai
Assistant Scientist III
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Koziel, Jacek
Professor Emeritus
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Jenks, William
Professor Emeritus
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van Leeuwen, Johannes
Professor Emeritus
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Civil, Construction and Environmental Engineering

The Department of Civil, Construction, and Environmental Engineering seeks to apply knowledge of the laws, forces, and materials of nature to the construction, planning, design, and maintenance of public and private facilities. The Civil Engineering option focuses on transportation systems, bridges, roads, water systems and dams, pollution control, etc. The Construction Engineering option focuses on construction project engineering, design, management, etc.

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The Department of Civil Engineering was founded in 1889. In 1987 it changed its name to the Department of Civil and Construction Engineering. In 2003 it changed its name to the Department of Civil, Construction and Environmental Engineering.

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1889-present

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  • Department of Civil Engineering (1889-1987)
  • Department of Civil and Construction Engineering (1987-2003)
  • Department of Civil, Construction and Environmental Engineering (2003–present)

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Agricultural and Biosystems Engineering

Since 1905, the Department of Agricultural Engineering, now the Department of Agricultural and Biosystems Engineering (ABE), has been a leader in providing engineering solutions to agricultural problems in the United States and the world. The department’s original mission was to mechanize agriculture. That mission has evolved to encompass a global view of the entire food production system–the wise management of natural resources in the production, processing, storage, handling, and use of food fiber and other biological products.

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In 1905 Agricultural Engineering was recognized as a subdivision of the Department of Agronomy, and in 1907 it was recognized as a unique department. It was renamed the Department of Agricultural and Biosystems Engineering in 1990. The department merged with the Department of Industrial Education and Technology in 2004.

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1905–present

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  • Department of Agricultural Engineering (1907–1990)

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Food Science and Human NutritionCivil, Construction and Environmental EngineeringAgricultural and Biosystems EngineeringToxicology
Abstract

Fermentation of sugar to produce ethanol also produces volatile byproducts. This study was aimed at purifying corn-based ethanol for industrial and pharmaceutical use. The research was on treatment for 10 impurities removal after distillation. The ethanol headspace was sampled with solid-phase microextraction and analyzed with gas chromatography–mass spectrometry. A 40 mg/L ozone treatment resulted in >56% and >36% removal of styrene and 2-pentylfuran, respectively, without significant generation of byproducts. A 60 g/L activated carbon (AC) treatment with 270 min adsorption time resulted in 84%, >72%, and >78% removal of ethyl hexanoate, ethyl octanoate, and ethyl decanoate respectively. CO2-based stripping, at 675 LStripping gas/LSample, removed 65%, >82%, and >83% acetaldehyde, ethyl vinyl ether, and 1,1-diethoxyethane respectively. A combination of three approaches effectively removes these 8 impurities.

Comments

This article is published as Onuki, Shinnosuke, Jacek A. Koziel, William S. Jenks, Lingshuang Cai, Somchai Rice, and J. Hans van Leeuwen. "Ethanol purification with ozonation, activated carbon adsorption, and gas stripping." Separation and Purification Technology 151 (2015): 165-171. DOI: 10.1016/j.seppur.2015.07.026. Posted with permission.

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Thu Jan 01 00:00:00 UTC 2015
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