Agricultural and Biosystems Engineering Publications

Campus Units

Agricultural and Biosystems Engineering, Civil, Construction and Environmental Engineering, Food Science and Human Nutrition, Toxicology

Document Type

Article

Publication Version

Submitted Manuscript

Publication Date

9-19-2018

Journal or Book Title

Preprints

First Page

2018090362

Research Focus Area(s)

Animal Production Systems Engineering

DOI

10.20944/preprints201809.0362.v1

Abstract

Determination of time-weighted average (TWA) concentrations of volatile organic compounds (VOCs) in air using solid-phase microextraction (SPME) is advantageous over other sampling techniques, but is often characterized by insufficient accuracies, particularly at longer sampling times. Experimental investigation of this issue and disclosing the origin of the problem is problematic and often not practically feasible due to high uncertainties. This research is aimed at developing the model of TWA extraction process and optimization of TWA air sampling by SPME using finite element analysis software (COMSOL Multiphysics). It was established that sampling by porous SPME coatings with high affinity to analytes is affected by slow diffusion of analytes inside the coating, an increase of analytes concentrations in the air near the fiber tip due to equilibration, and eventual lower sampling rate. The increase of a fiber retraction depth (Z) resulted in better recoveries. Sampling of studied VOCs using 23-ga Car/PDMS assembly at maximum possible Z(40 mm) was proven to provide more accurate results. Alternative sampling configuration based on 78.5 x 0.75 mm i.d. SPME liner was proven to provide similar accuracy at improved detection limits. Its modification with the decreased internal diameter from the sampling side should provide even better recoveries. The developed model offers new insight into optimization of air and gas sampling using SPME.

Comments

This is a pre-print of the article Kenessov, Bulat, Jacek A. Koziel, Nassiba Baimatova, Olga P. Demyanenko, and Miras Derbissalin. "Optimization of Time-Weighted Average Air Sampling by Solid-Phase Microextraction Fibers Using Finite Element Analysis Software." Preprints (2018): 2018090362. DOI: 10.20944/preprints201809.0362.v1 Posted with permission.

Creative Commons License

Creative Commons Attribution 4.0 License
This work is licensed under a Creative Commons Attribution 4.0 License.

Copyright Owner

The Authors

Language

en

File Format

application/pdf

Published Version

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