Campus Units

Agronomy, Electrical and Computer Engineering

Document Type

Article

Publication Version

Submitted Manuscript

Publication Date

7-18-2019

Journal or Book Title

ACS Applied Materials & Interfaces

DOI

10.1021/acsami.9b07120

Abstract

There is an unmet need for improved fertilizer management in agriculture. Continuous monitoring of soil nitrate would address this need. This paper reports an all-solid-state miniature potentiometric soil sensor that works in direct contact with soils to monitor nitrate-nitrogen (NO3--N) in soil solution with parts-per-million (ppm) resolution. A working electrode is formed from a novel nanocomposite of poly(3-octyl-thiophene) and molybdenum disulfide (POT–MoS2) coated on a patterned Au electrode and covered with a nitrate-selective membrane using a robotic dispenser. The POT–MoS2 layer acts as an ion-to-electron transducing layer with high hydrophobicity and redox properties. The modification of the POT chain with MoS2 increases both conductivity and anion exchange, while minimizing the formation of a thin water layer at the interface between the Au electrode and the ion-selective membrane, which is notorious for solid-state potentiometric ion sensors. Therefore, the use of POT–MoS2 results in an improved sensitivity and selectivity of the working electrode. The reference electrode comprises a screen-printed silver/silver chloride (Ag/AgCl) electrode covered by a protonated Nafion layer to prevent chloride (Cl-) leaching in long-term measurements. This sensor was calibrated using both standard and extracted soil solutions, exhibiting a dynamic range that includes all concentrations relevant for agricultural applications (1–1500 ppm NO3--N). With the POT–MoS2 nanocomposite, the sensor offers a sensitivity of 64 mV/decade for nitrate detection, compared to 48 and 38 mV/decade for POT and MoS2 alone, respectively. The sensor was embedded into soil slurries where it accurately monitored nitrate for a duration of 27 days.

Comments

This is a manuscript of an article publsihed as Ali, Md Azahar, Xinran Wang, Yuncong Chen, Yueyi Jiao, Navreet K. Mahal, Satyanarayana Moru, Michael J. Castellano, James C. Schnable, Patrick Schnable, and Liang Dong. "Continuous Monitoring of Soil Nitrate Using a Miniature Sensor with Poly (3-octyl-thiophene) and Molybdenum Disulfide Nanocomposite." ACS Applied Materials & Interfaces (2019). doi: 10.1021/acsami.9b07120. Posted with permission.

Copyright Owner

American Chemical Society

Language

en

File Format

application/pdf

Published Version

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