Reactions of uranium carbide in a fused KC1-LiC1/zince system

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1964-11-01
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Robinson, William
Chiotti, Premo
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Ames National Laboratory

Ames National Laboratory is a government-owned, contractor-operated national laboratory of the U.S. Department of Energy (DOE), operated by and located on the campus of Iowa State University in Ames, Iowa.

For more than 70 years, the Ames National Laboratory has successfully partnered with Iowa State University, and is unique among the 17 DOE laboratories in that it is physically located on the campus of a major research university. Many of the scientists and administrators at the Laboratory also hold faculty positions at the University and the Laboratory has access to both undergraduate and graduate student talent.

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Abstract

The reaction of uranium monocarbide with liquid zinc was investigated in the temperature range of 540-800° C. At temperatures below 725° C the uranium monocarbide reacts with the liquid zinc to form a uranium-zinc compound and an oxygen enriched uranium monocarbide phase. There is no reaction at 800° C. This indicates that the standard free energy of formation of uranium monocarbide is equal to the free energy of UZn8 . 5 at about 725°C. No other uranium carbide phase is ever observed as a reaction product.

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