Publication Date

2018

Department

Ames Laboratory; Chemistry

Campus Units

Chemistry, Ames Laboratory

Report Number

IS-J 9677

DOI

10.1039/C8CC03186J

Journal Title

Chemical Communications

Abstract

A new bulky silazido ligand, –N(SiHMe2)Dipp (Dipp = C6H3-2,6-iPr2) supports planar, three-coordinate homoleptic rare earth complexes Ln{N(SiHMe2)Dipp}3 (Ln = Sc, Y, Lu) that each contain three secondary Ln↼HSi interactions and one agostic CH bond. Y{N(SiHMe2)Dipp}3 and acetophenone react via hydrosilylation, rather than by insertion into the Y–N bond or enolate formation.

Language

en

Department of Energy Subject Categories

36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Publisher

Iowa State University Digital Repository, Ames IA (United States)

Available for download on Tuesday, January 01, 2019

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