Title
Bulk single crystal growth and sample surface preparation of catalytic NaAu 2
Publication Date
2-21-2019
Department
Ames Laboratory; Chemistry; Materials Science and Engineering
Campus Units
Chemistry, Materials Science and Engineering, Ames Laboratory
OSTI ID+
1498713
Report Number
IS-J 9657
DOI
10.1016/j.jallcom.2019.02.204
Journal Title
Journal of Alloys and Compounds
Volume Number
789
First Page
362
Last Page
366
Abstract
Here in we have grown bulk single crystals of NaAu2 for the first time to enable surface studies on the nature of the (111) bulk surface. This intermetallic compound exhibits surprisingly high catalytic activity for CO oxidation, a benchmark reaction. Theory predicts NaAu2 to be the most thermodynamically stable composition in the Na-Au binary phase diagram and NaAu2 has been seen to preferentially form in experiments containing Na and Au which supports this prediction. The (111) surface was also predicted to be the most stable and is nearly bulk-terminated making single crystal samples prepared with this crystallographic orientation a fitting choice. The crystal quality and surface composition of the metallographically prepared surface was determined by x-ray diffraction methods in addition to optical and electron microscopy.
DOE Contract Number(s)
AC02-07CH11358; 200021-129511
Language
en
Department of Energy Subject Categories
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Publisher
Iowa State University Digital Repository, Ames IA (United States)
