Rapid and ordered carbonylation and oxygenation of a cobalt(II) methyl
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2017-01-01
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Ames National LaboratoryChemistry
Abstract
The oxidative carbonylation of ToMCoMe (1; ToM = tris(4,4-dimethyl-2-oxazolinyl)phenylborate) involves its rapid, reversible reaction with CO to form ToMCo{C(O)Me}CO (2) followed by rapid reaction with O2 yielding ToMCoOAc (3), in contrast to the slow direct carboxylation of ToMCoMe by CO2.