Publication Date

2017

Department

Ames Laboratory; Chemistry

Campus Units

Chemistry, Ames Laboratory

Report Number

IS-J 9445

DOI

10.1039/C7CC06339C

Journal Title

Chemical Communications

Volume Number

53

First Page

11020

Last Page

11023

Abstract

The oxidative carbonylation of ToMCoMe (1; ToM = tris(4,4-dimethyl-2-oxazolinyl)phenylborate) involves its rapid, reversible reaction with CO to form ToMCo{C(O)Me}CO (2) followed by rapid reaction with O2 yielding ToMCoOAc (3), in contrast to the slow direct carboxylation of ToMCoMe by CO2.

Language

en

Department of Energy Subject Categories

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Publisher

Iowa State University Digital Repository, Ames IA (United States)

Available for download on Saturday, September 15, 2018

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