Publication Date

4-2-2020

Department

Ames Laboratory; Chemistry

Campus Units

Ames Laboratory, Chemistry

OSTI ID+

1608064

Report Number

IS-J 10205

DOI

10.3389/fchem.2020.00186

Journal Title

Frontiers in Chemistry

Volume Number

8

First Page

186

Abstract

Flux crystal growth has been widely applied to explore new phases and grow crystals of emerging materials. To accommodate the needs of high-quality single crystals, the flux crystal growth should be reliable, controllable, and predictable. The selections of suitable flux and growth conditions remain empirical due to the lack of systematic investigation especially for reactions, which involve highly volatile components, such as P and As. Considering the flux elements, often the system in question is a quaternary or a higher multinary system, which drastically increases complexity. In this manuscript, on the examples of flux growth of phosphides and arsenides, guidelines of flux selections, existing challenges, and future directions are discussed. We expect that the field will be further developed by applying in situ techniques and computational modeling of the nucleation and growth kinetics. Additionally, leveraging variables other than temperature, such as applied pressure, will make flux growth a more powerful tool in the future.

DOE Contract Number(s)

AC02-07CH11358

Language

en

Publisher

Iowa State University Digital Repository, Ames IA (United States)

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