Publication Date

3-27-2020

Department

Ames Laboratory

Campus Units

Ames Laboratory

OSTI ID+

1703818

Report Number

IS-J 10183

DOI

10.1016/j.intermet.2020.106764

Journal Title

Intermetallics

Volume Number

121

First Page

106764

Abstract

Relaxation behaviors of highly rejuvenated Zr50Cu40Al10 bulk metallic glass was investigated using synchrotron X-ray scattering coupled with differential scanning calorimetry. The relaxation of rejuvenated volume is found to correspond to a marked exothermic event prior to the glass transition. High-energy synchrotron X-ray measurements of the structure factor show that annihilation of rejuvenated volume correspond to a sharpening of the scattering peaks. The calculated reduced pair distribution function suggests that the atomic re-arrangement in the second shell are largely responsible for the reduction in the free volume and decrease in full-width at half-maximum of the Total Structure Factor observed during structural relaxation. Mechanical properties in the highly rejuvenated metallic glass were evaluated as a function of annealing temperature.

DOE Contract Number(s)

AC02-07CH11358; AC02-06CH11357

Language

en

Publisher

Iowa State University Digital Repository, Ames IA (United States)

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