Antiferromagnetism in semiconducting SrMn2Sb2 and BaMn2Sb2 single crystals

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2018-01-03
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Sangeetha, N.
Smetana, V.
Johnston, David
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Physics and Astronomy
Physics and astronomy are basic natural sciences which attempt to describe and provide an understanding of both our world and our universe. Physics serves as the underpinning of many different disciplines including the other natural sciences and technological areas.
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Ames National LaboratoryPhysics and Astronomy
Abstract

Crystals of SrMn 2 Sb 2 and BaMn 2 Sb 2 were grown using Sn flux and characterized by powder and single-crystal x-ray diffraction, respectively, and by single-crystal electrical resistivity ρ , heat capacity C p , and magnetic susceptibility χ measurements versus temperature T , and magnetization versus field M ( H ) isotherm measurements. SrMn 2 Sb 2 adopts the trigonal CaAl 2 Si 2 -type structure, whereas BaMn 2 Sb 2 crystallizes in the tetragonal ThCr 2 Si 2 -type structure. The ρ ( T ) data indicate semiconducting behaviors for both compounds with activation energies of ≳ 0.35 eV for SrMn 2 Sb 2 and 0.16 eV for BaMn 2 Sb 2 . The χ ( T ) and C p ( T ) data reveal antiferromagnetic (AFM) ordering at T N = 110 K for SrMn 2 Sb 2 and 450 K for BaMn 2 Sb 2 . The anisotropic χ ( T ≤ T N ) data also show that the ordered moments in SrMn 2 Sb 2 are aligned in the hexagonal a b plane, whereas the ordered moments in BaMn 2 Sb 2 are aligned collinearly along the tetragonal c axis. The a b -plane M ( H ) data for SrMn 2 Sb 2 exhibit a continuous metamagnetic transition at low fields 0 < H ≲ 1 T, whereas BaMn 2 Sb 2 exhibits no metamagnetic transitions up to 5.5 T. The χ ( T ) and C p ( T ) data for both SrMn 2 Sb 2 and BaMn 2 Sb 2 indicate strong dynamic short-range AFM correlations above their respective T N up to at least 900 K within a local-moment picture, corresponding to quasi-two-dimensional magnetic behavior. The present results and a survey of the literature for Mn pnictides with the CaAl 2 Si 2 and ThCr 2 Si 2 crystal structures show that the T N values for the CaAl 2 Si 2 -type compounds are much smaller than those for the ThCr 2 Si 2 -type materials.

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