Magnetic structures and interplay between rare-earth Ce and Fe magnetism in single-crystal CeFeAsO

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2013-11-01
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Zhang, Qiang
Tan, Wei
Li, Haifeng
Kim, Jong-Woo
Yan, Jiaqiang
McCallum, R.
Lograsso, Thomas
Zarestky, Jerel
Bud’ko, Sergey
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Lograsso, Thomas
Ames Laboratory Division Director
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Physics and Astronomy
Physics and astronomy are basic natural sciences which attempt to describe and provide an understanding of both our world and our universe. Physics serves as the underpinning of many different disciplines including the other natural sciences and technological areas.
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Materials Science and Engineering
Materials engineers create new materials and improve existing materials. Everything is limited by the materials that are used to produce it. Materials engineers understand the relationship between the properties of a material and its internal structure — from the macro level down to the atomic level. The better the materials, the better the end result — it’s as simple as that.
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Ames National LaboratoryPhysics and AstronomyMaterials Science and Engineering
Abstract

Neutron and synchrotron resonant x-ray magnetic scattering (RXMS) complemented by heat capacity and resistivity measurements reveal the evolution of the magnetic structures of Fe and Ce sublattices in a CeFeAsO single crystal. The RXMS of magnetic reflections at the Ce L-II edge shows a magnetic transition that is specific to the Ce antiferromagnetic long-range ordering at T-Ce approximate to 4 K with short-range Ce ordering above T-Ce, whereas neutron diffraction measurements of a few magnetic reflections indicate a transition at T* approximate to 12 K with an unusual order parameter. Detailed order-parameter measurements on several magnetic reflections by neutrons show a weak anomaly at 4 K that we associate with the Ce ordering. The successive transitions at T-Ce and T* can also be clearly identified by two anomalies in heat capacity and resistivity measurements. The higher transition temperature at T* approximate to 12 K is mainly ascribed to Fe spin reorientation transition, below which Fe spins rotate uniformly and gradually in the ab plane. The Fe spin reorientation transition and short-range Ce ordering above T-Ce reflect the strong Fe-Ce couplings prior to long-range ordering of the Ce. The evolution of the intricate magnetic structures in CeFeAsO going through T* and T-Ce is proposed.

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This article is published as Zhang, Qiang, Wei Tian, Haifeng Li, Jong-Woo Kim, Jiaqiang Yan, R. William McCallum, Thomas A. Lograsso et al. "Magnetic structures and interplay between rare-earth Ce and Fe magnetism in single-crystal CeFeAsO." Physical Review B88, no. 17 (2013): 174517. DOI: 10.1103/PhysRevB.88.174517. Posted with permission.

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Tue Jan 01 00:00:00 UTC 2013
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