Campus Units

Ames Laboratory, Materials Science and Engineering

Document Type

Article

Publication Version

Accepted Manuscript

Publication Date

6-25-2019

Journal or Book Title

Journal of Alloys and Compounds

Volume

790

First Page

1119

Last Page

1126

DOI

10.1016/j.jallcom.2019.03.250

Abstract

We present a design concept for developing ZrB2-SiC-AlN composites with enhanced oxidative stability at ultra-high temperatures (∼2000 °C) and low pressures (100 Torr). The oxidative stability of these materials arises from a protective silica based scale. However, active oxidation of SiC above 1700 °C presents a challenge, which we circumvent through the in-situ growth of a zirconia layer that serves as a thermal barrier, ensuring that the effective temperature at the zirconia/Si rich subscale is less than the active oxidation temperature. The design concept is validated by a series of ultra-high temperature oxidation experiments under static as well as cyclic conditions.

Comments

This is a manuscript of an article published as Ouyang, Gaoyuan, Matthew F. Besser, Matthew J. Kramer, Mufit Akinc, and Pratik K. Ray. "Designing oxidation resistant ultra-high temperature ceramics through the development of an adherent native thermal barrier." Journal of Alloys and Compounds 790 (2019): 1119-1126. DOI: 10.1016/j.jallcom.2019.03.250. Posted with permission.

Creative Commons License

Creative Commons Attribution-Noncommercial-No Derivative Works 4.0 License
This work is licensed under a Creative Commons Attribution-Noncommercial-No Derivative Works 4.0 License.

Copyright Owner

Elsevier B.V.

Language

en

File Format

application/pdf

Available for download on Saturday, March 20, 2021

Published Version

Included in

Metallurgy Commons

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