Flux requirements for the growth of RFeAsO (R = rare earth) superconductors
Date
Authors
Major Professor
Advisor
Committee Member
Journal Title
Journal ISSN
Volume Title
Publisher
Authors
Research Projects
Organizational Units
Journal Issue
Is Version Of
Versions
Series
Department
Abstract
Millimeter-sized LaFeAsO single crystals have been successfully grown out of NaAs flux starting with (LaAs+1/2Fe2O3):20NaAs. The factors which allow the growth of these crystals out of NaAs but not out of many other fluxes, such as FeAs, have been investigated. X-ray powder diffraction found that NaAs synthesized for the growth ofRFeAsO superconductors has monoclinic LiAs structure. Thermal analysis confirmed that NaAs melts congruently at about 600 °C. The ability to extract RFeAsO crystals from this NaAs flux suggests that NaAs has a significant oxygen solubility, possibly due to the formation of the ternary compound NaAsO2, and enough oxygen diffusivity to transport solute to the growth front. Oxygen solubility and diffusivity are two important factors in searching for an alternative environmentally benign flux for the growth of RFeAsOsuperconductors.
Comments
The following article appeared in Applied Physics Letters 98 (2011): 072504 and can be found at http://dx.doi.org/10.1063/1.3555632.