The Morphotropic Phase Boundary in the (1-x)PbZrO3–x[0.3Bi(Zn1/2Ti1/2)O3–0.7PbTiO3] Perovskite Solid Solution

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2012-01-01
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Sareein, T.
Hu, W.
Tan, Xiaoli
Yimnirun, R.
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Tan, Xiaoli
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Materials Science and Engineering
Materials engineers create new materials and improve existing materials. Everything is limited by the materials that are used to produce it. Materials engineers understand the relationship between the properties of a material and its internal structure — from the macro level down to the atomic level. The better the materials, the better the end result — it’s as simple as that.
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Abstract

Ceramics in the (1-x)PbZrO3–x[0.3Bi(Zn1/2Ti1/2)O3–0.7PbTiO3] solid solution system with 0.48  x  0.56 were investigated. A morphotropic phase boundary separating rhombohedral and tetragonal perovskite phases was identified at x = 0.52. This composition displays the maximum remanent polarization Pr of 40.7 μC/cm2 and the best piezoelectric coefficient d33 of 311 pC/N in the pseudo-binary system. However, the Curie temperature Tc for this MPB composition is 291 °C, much lower than initially expected.

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This is a manuscript of an article from Journal of Materials Science 47, 1774-1779 (2012). DOI: 10.1007/s10853-011-5961-2. Posted with permission. The final publication is available at Springer via http://dx.doi.org/10.1007/s10853-011-5961-2.

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Sun Jan 01 00:00:00 UTC 2012
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