Synthesis and Structure of a Tetrasilacyclohexyne
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Ames National Laboratory is a government-owned, contractor-operated national laboratory of the U.S. Department of Energy (DOE), operated by and located on the campus of Iowa State University in Ames, Iowa.
For more than 70 years, the Ames National Laboratory has successfully partnered with Iowa State University, and is unique among the 17 DOE laboratories in that it is physically located on the campus of a major research university. Many of the scientists and administrators at the Laboratory also hold faculty positions at the University and the Laboratory has access to both undergraduate and graduate student talent.
The Department of Chemistry seeks to provide students with a foundation in the fundamentals and application of chemical theories and processes of the lab. Thus prepared they me pursue careers as teachers, industry supervisors, or research chemists in a variety of domains (governmental, academic, etc).
History
The Department of Chemistry was founded in 1880.
Dates of Existence
1880-present
Related Units
- College of Liberal Arts and Sciences (parent college)
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Abstract
Although strained cycloalkynes have received considerable experimentaJ2 and theoreticaJ3 attention for many years, the smallest isolable rings are seven-membered.4 We report here the synthesis, chemical and structural characterization, and ab initio calculations of the first isolable5 six-membered ring containing a carbon-carbon triple bond.
Comments
Reprinted (adapted) with permission from Journal of the American Chemical Society 114 (1992): 4920, doi:10.1021/ja00038a077. Copyright 1992 American Chemical Society.