Phase transition in bulk single crystals and thin films of VO2 by nanoscale infrared spectroscopy and imaging

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2015-06-15
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Liu, Mengkun
Sternbach, Aaron
Wagner, Martin
Slusar, Tetiana
Bud'ko, Sergey
Kittiwatanakul, Salinporn
Qazilbash, M.
McLeod, Alexander
Fei, Zhe
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Canfield, Paul
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Ames National Laboratory
Abstract

We have systematically studied a variety of vanadium dioxide (VO2) crystalline forms, including bulk single crystals and oriented thin films, using infrared (IR) near-field spectroscopic imaging techniques. By measuring the IR spectroscopic responses of electrons and phonons in VO2 with sub-grain-size spatial resolution (∼20nm), we show that epitaxial strain in VO2 thin films not only triggers spontaneous local phase separations, but also leads to intermediate electronic and lattice states that are intrinsically different from those found in bulk. Generalized rules of strain- and symmetry-dependent mesoscopic phase inhomogeneity are also discussed. These results set the stage for a comprehensive understanding of complex energy landscapes that may not be readily determined by macroscopic approaches.

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This article was published in Physical Review B 91 (2015): 245155, doi:10.1103/PhysRevB.91.245155. Posted with permission

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Thu Jan 01 00:00:00 UTC 2015
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