Equilibrium microstructures of diblock copolymers under 3D confinement

Thumbnail Image
Date
2019-01-01
Authors
Tenneti, Ananth
Ackerman, David
Ganapathysubramanian, Baskar
Major Professor
Advisor
Committee Member
Journal Title
Journal ISSN
Volume Title
Publisher
Authors
Person
Research Projects
Organizational Units
Organizational Unit
Mechanical Engineering
The Department of Mechanical Engineering at Iowa State University is where innovation thrives and the impossible is made possible. This is where your passion for problem-solving and hands-on learning can make a real difference in our world. Whether you’re helping improve the environment, creating safer automobiles, or advancing medical technologies, and athletic performance, the Department of Mechanical Engineering gives you the tools and talent to blaze your own trail to an amazing career.
Organizational Unit
Electrical and Computer Engineering

The Department of Electrical and Computer Engineering (ECpE) contains two focuses. The focus on Electrical Engineering teaches students in the fields of control systems, electromagnetics and non-destructive evaluation, microelectronics, electric power & energy systems, and the like. The Computer Engineering focus teaches in the fields of software systems, embedded systems, networking, information security, computer architecture, etc.

History
The Department of Electrical Engineering was formed in 1909 from the division of the Department of Physics and Electrical Engineering. In 1985 its name changed to Department of Electrical Engineering and Computer Engineering. In 1995 it became the Department of Electrical and Computer Engineering.

Dates of Existence
1909-present

Historical Names

  • Department of Electrical Engineering (1909-1985)
  • Department of Electrical Engineering and Computer Engineering (1985-1995)

Related Units

Journal Issue
Is Version Of
Versions
Series
Department
Mechanical EngineeringElectrical and Computer EngineeringPlant Sciences Institute
Abstract

We investigate equilibrium microstructures exhibited by diblock copolymers in confined 3D geometries. We perform Self-Consistent Field Theory (SCFT) simulations using a finite-element based computational framework (Ackerman et al. 2017), that provides the flexibility to compute equilibrium structures under arbitrary geometries. We consider a sequence of 3D geometries (tetrahedron to sphere) that have the same volume but exhibit varying curvature. This allows us to study the interplay between edge and curvature effects of the 3D geometries on the equilibrium microstructures. We observe that beyond a length scale, the equilibrium structure changes from an interconnected network to a multi-layered concentric shell as the curvature of the 3D geometry is reduced. However, below this length scale the equilibrium structure remains a multi-layered concentric shell independent of curvature. We additionally explore variations in the equilibrium microstructures at a few discrete volume fractions. This study provides insight into possible frustrated phases that can arise in AB diblock systems while varying the shape of confinement geometry.

Comments

This is a pre-print of the article Tenneti, Ananth, David M. Ackerman, and Baskar Ganapathysubramanian. "Equilibrium microstructures of diblock copolymers under 3D confinement." arXiv preprint arXiv:1910.09088 (2019). Posted with permission.

Description
Keywords
Citation
DOI
Source
Copyright
Tue Jan 01 00:00:00 UTC 2019
Collections