The ability of metal alloys to rapidly oxidize in ambient condition presents both a challenge and an opportunity. Herein, we focus on opportunities buried in the passivating oxide of liquid metal particles. Recently described sub-surface com-plexity and order present an opportunity to frustrate homogeneous nucleation hence enhanced undercooling. Plasticity of the underlying liquid metal surface offers an autonomously repairing sub-surface hence the lowest E0 component domi-nates the surface unless stoichiometrically limited. This plasticity provides an opportunity to synthesize organometallic polymers that in situ self-assemble to high aspect ratio nanomaterials. An induced surface speciation implies that under the appropriate oxidant tension, the oxide thickness and composition can be tuned, leading to temperature-dependent composition inversion and so-called chameleon metals. The uniqueness of demonstrated capabilities points to the need for more exploration in this small but rather complex part of a metal alloy.