Synthesis of a pentacyclic precursor to the Strychnos alkaloids
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1990-03-01
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Kraus, George
University Professor Emeritus
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Chemistry
Abstract
An advanced intermediate for the synthesis of the Strychnos alkaloids was constructed by a sequence involving an intramolecular Diels-Alder reaction, alkylation of an enol silyl ether, and conversion of the alkylation product into a pentacyclic lactam.
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Reprinted (adapted) with permission from The Journal of Organic Chemistry, 55(5); 1624-1627. Doi: 10.1021/jo00292a042. Copyright 1990 American Chemical Society.
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Mon Jan 01 00:00:00 UTC 1990