Facile Syntheses of Titanium(II), Tin(II), and Vanadium(II) Porphyrin Complexes through Homogeneous Reduction. Reactivity of trans-(TTP)TiL2 (L = THF, t-BuNC)
Date
1998
Authors
Major Professor
Advisor
Committee Member
Journal Title
Journal ISSN
Volume Title
Publisher
Authors
Person
Research Projects
Organizational Units
Organizational Unit
Journal Issue
Is Version Of
Versions
Series
Department
Chemistry
Abstract
Facile syntheses of the meso-tetra-p-tolylporphyrin (TTP) complexes trans-(TTP)Ti(THF)2(1), (TTP)Sn (2), and trans-(TTP)V(THF)2 (3) are achieved through homogeneous reduction of high-valent precursors using NaBEt3H. The composition of the new compound trans-(TTP)Ti(THF)2 was determined by spectroscopic and chemical characterization. Ligand displacement reactions of trans-(TTP)Ti(THF)2 with t-BuNC produced a new Ti(II) complex,trans-(TTP)Ti(t-BuNC)2. The ligand-binding preference of (TTP)TiIILn (n = 1, 2) is picoline ∼pyridine > t-BuNC > PhC⋮CPh > EtC⋮CEt > THF.
Comments
Reprinted (adapted) with permission from Inorganic Chemistry 37 (1998): 5, doi:10.1021/ic970961n. Copyright 1998 American Chemical Society.
Description
Keywords
Citation
DOI
Subject Categories
Copyright
Thu Jan 01 00:00:00 UTC 1998