Campus Units

Chemistry, Ames Laboratory

Document Type

Article

Publication Version

Published Version

Publication Date

2017

Journal or Book Title

Chemical Communications

Volume

53

Issue

4

First Page

716

Last Page

719

DOI

10.1039/C6CC09304C

Abstract

A β-SiH functionalized benzyl anion [C(SiHMe2)2Ph]− is obtained by deprotonation of HC(SiHMe2)2Ph with KCH2Ph or by reaction of KOtBu and (Me2HSi)3CPh; LnI3(THF)n and three equivalents of this carbanion combine to provide homoleptic tris(alkyl)lanthanide compounds Ln{C(SiHMe2)2Ph}3 (Ln = La, Ce, Pr, Nd) containing secondary metal–ligand interactions.

Comments

This article is published as Boteju, Kasuni C., Arkady Ellern, and Aaron D. Sadow. "Homoleptic organolanthanide compounds supported by the bis (dimethylsilyl) benzyl ligand." Chemical Communications 53, no. 4 (2017): 716-719. 10.1039/C6CC09304C

Creative Commons License

Creative Commons Attribution 3.0 License
This work is licensed under a Creative Commons Attribution 3.0 License.

Copyright Owner

Royal Society of Chemistry

Language

en

File Format

application/pdf

Included in

Chemistry Commons

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