Campus Units
Chemistry, Ames Laboratory
Document Type
Article
Publication Version
Accepted Manuscript
Publication Date
1-9-2017
Journal or Book Title
Angewandte Chemie International
Volume
56
Issue
2
First Page
628
Last Page
631
DOI
10.1002/anie.201610263
Abstract
The homoleptic organocerium complex Ce{C(SiHMe2)3}3 (1) reacts with B(C6F5)3 to produce the zwitterionic bis(alkyl) hydridoborato Ce{C(SiHMe2)3}2HB(C6F5)3 (2). NMR and IR spectroscopy and X-ray crystallography indicate that each alkyl ligand contains two bridging Ce↼H-Si interactions in both 1 and 2. Compound 2 serves as a precatalyst for the hydrosilylation of acrylates to give α-silyl esters at room temperature with a turnover number of 2200.
Copyright Owner
Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Copyright Date
2017
Language
en
File Format
application/pdf
Recommended Citation
Pindwal, Aradhana; Patnaik, Smita; Everett, William C.; Ellern, Arkady; Windus, Theresa L.; and Sadow, Aaron D., "Cerium-Catalyzed Hydrosilylation of Acrylates to Give α-Silyl Esters" (2017). Chemistry Publications. 1009.
https://lib.dr.iastate.edu/chem_pubs/1009
Comments
This is the peer reviewed version of the following article: Pindwal, Aradhana, Smita Patnaik, William C. Everett, Arkady Ellern, Theresa L. Windus, and Aaron D. Sadow. "Cerium‐Catalyzed Hydrosilylation of Acrylates to Give α‐Silyl Esters." Angewandte Chemie International Edition 56, no. 2 (2017): 628-631, which has been published in final form at DOI:10.1002/anie.201610263. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.