Campus Units

Chemistry, Mechanical Engineering, Ames Laboratory

Document Type

Article

Publication Version

Accepted Manuscript

Publication Date

3-29-2017

Journal or Book Title

Chemistry - A European Journal

Volume

23

Issue

18

First Page

4266

Last Page

4270

DOI

10.1002/chem.201605852

Abstract

The facile pyrolysis of a bipyridyl metal‐organic framework, MOF‐253, produces N‐doped porous carbons (Cz‐MOF‐253), which exhibit excellent catalytic activity in the Knoevenagel condensation reaction and outperform other nitrogen‐containing MOF‐derived carbons. More importantly, by virtue of their high Lewis basicity and porous nature, Cz‐MOF‐253‐supported Pd nanoparticles (Pd/Cz‐MOF‐253‐800) show excellent performance in a one‐pot sequential Knoevenagel condensation‐hydrogenation reaction.

Comments

This is the peer-reviewed version of the following article: Li, Xinle, Biying Zhang, Yuhui Fang, Weijun Sun, Zhiyuan Qi, Yuchen Pei, Shuyan Qi et al. "Metal–Organic‐Framework‐Derived Carbons: Applications as Solid‐Base Catalyst and Support for Pd Nanoparticles in Tandem Catalysis." Chemistry-A European Journal 23, no. 18 (2017): 4266-4270, which has been published in final form at doi: 10.1002/chem.201605852. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. Posted with permission.

Copyright Owner

Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim

Language

en

File Format

application/pdf

Published Version

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