Campus Units
Chemistry, Materials Science and Engineering, Physics and Astronomy, Ames Laboratory
Document Type
Article
Publication Version
Accepted Manuscript
Publication Date
11-18-2019
Journal or Book Title
Physical Chemistry Chemical Physics
DOI
10.1039/C9CP03449H
Abstract
Experimental data from low-temperature Scanning Tunneling Microscopy (LTSTM) studies on coinage metal surfaces with very low coverages of S is providing new insights into metal-S interactions. A previous LTSTM study for Cu(100), and a new analysis reported here for Ag(100), both indicate no metal-sulfur complex formation, but an Au4S5 complex was observed previously on Au(100). In marked contrast, various complexes have been proposed and/or observed on Ag(111) and Cu(111), but not on Au(111). Also, exposure to trace amounts of S appears to enhance mass transport far more dramatically on (111) than on (100) surfaces for Cu and Ag, a feature tied to the propensity for complex formation. Motivated by these observations, we present a comprehensive assessment at the level of DFT to assess the existence and stability of complexes on (100) surfaces, and compare results with previous analyses for (111) surfaces. Consistent with experiment, our DFT analysis finds no stable complexes on Ag(100) and Cu(100), but several exist for Au(100). In addition, we systematically relate stability for adsorbed and gas-phase species within the framework of Hess`s law. We thereby provide key insight into the various energetic contributions to stability which in turn elucidates the difference in behavior between (100) and (111) surfaces.
Creative Commons License
This work is licensed under a Creative Commons Attribution-Noncommercial 3.0 License
Copyright Owner
The Royal Society of Chemistry
Copyright Date
2019
Language
en
File Format
application/pdf
Recommended Citation
Liu, Da-Jiang; Spurgeon, Peter M.; Lee, Jiyoung; Windus, Theresa L.; Thiel, Patricia A.; and Evans, James W., "Sulfur adsorption on coinage metal (100) surfaces: Propensity for metal-sulfur complex formation relative to (111) surfaces" (2019). Chemistry Publications. 1182.
https://lib.dr.iastate.edu/chem_pubs/1182
Comments
This is a manuscript of an article published as Liu, Da-Jiang, Peter Michael Spurgeon, Jiyoung Lee, Theresa L. Windus, Patricia Ann Thiel, and James W. Evans. "Sulfur adsorption on coinage metal (100) surfaces: Propensity for metal-sulfur complex formation relative to (111) surfaces." Physical Chemistry Chemical Physics (2019). DOI: 10.1039/C9CP03449H. Posted with permission.