Campus Units

Chemistry, Ames Laboratory

Document Type

Article

Publication Version

Published Version

Publication Date

5-7-2008

Journal or Book Title

Organometallics

Volume

27

Issue

11

First Page

2399

Last Page

2401

DOI

10.1021/om800252p

Abstract

The first example of a new class of oxazoline-based scorpionate ligand, tris(4,4-dimethyl-2-oxazolinyl)phenyl borate, [ToM]−, is prepared by reaction of 2-lithio-4,4-dimethyl-2-oxazolide and 0.3 equiv of dichlorophenylborane. The steric bulk of this ligand is greater than that of tris(3,5-Me2-pyrazolyl)borate (Tp*), as quantified by comparison of solid angles of crystallographically characterized zirconium(IV) complexes.

Comments

Reprinted (adapted) with permission from Organometallics 27 (2008): 2399, doi:10.1021/om800252p. Copyright 2008 American Chemical Society.

Copyright Owner

American Chemical Society

Language

en

File Format

application/pdf

Included in

Chemistry Commons

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