Campus Units

Ames Laboratory, Chemistry

Document Type

Article

Publication Version

Published Version

Publication Date

2015

Journal or Book Title

Inorganic Chemistry

Volume

54

Issue

1

First Page

200

Last Page

204

DOI

10.1021/ic502116k

Abstract

A new porphyrin-based microporous MOF, {Mn(II)0.5[Mn(II)4Cl(Mn(III)Cl-ttzpp)2(H2O)4]}·(DEF)20·(CH3OH)18·(H2O)12 (UTSA-57), has been constructed from {5,10,15,20-tetrakis[4-(2,3,4,5-tetrazolyl)phenyl]porphyrinato} manganese(III) chloride as the metalloligand. The MOF adopts the rare scu topology with one-dimensional square nanotube-like channels of about 20 Å. UTSA-57a exhibits permanent porosity and displays moderately high performance for C2H2/CH4 separation at room temperature.

Comments

Reprinted (adapted) with permission from Inorg. Chem., 2015, 54 (1), pp 200–204. Copyright 2015 American Chemical Society

Copyright Owner

American Chemical Society

Language

en

File Format

application/pdf

Share

COinS