Campus Units
Chemistry
Document Type
Article
Publication Version
Published Version
Publication Date
2-1998
Journal or Book Title
Journal of the American Chemical Society
Volume
120
Issue
9
First Page
2124
Last Page
2130
DOI
10.1021/ja9722077
Abstract
Proton-transfer reactions involving the silaformyl anion, HSiO-, and its conjugate acids, HSiOH and H2SiO, have been investigated with ab initio methods. Calculations through fourth-order perturbation theory suggest possible routes for proton transfer. Accurate estimates for the acidity of H2SiO and HSiOH are presented and discussed in light of earlier experimental estimates.
Copyright Owner
American Chemical Society
Copyright Date
1998
Language
en
File Format
application/pdf
Recommended Citation
Rusho, Jon A.; Gordon, Mark S.; Damrauer, Niels H.; and Damrauer, Robert, "A Computational Study of the Proton-Transfer Chemistry of the Silaformyl Anion" (1998). Chemistry Publications. 312.
https://lib.dr.iastate.edu/chem_pubs/312
Comments
Reprinted (adapted) with permission from Journal of the American Chemical Society 120 (1998): 2124, doi:10.1021/ja9722077. Copyright 1998 American Chemical Society.