Campus Units

Chemistry

Document Type

Article

Publication Version

Published Version

Publication Date

2-1998

Journal or Book Title

Journal of the American Chemical Society

Volume

120

Issue

9

First Page

2124

Last Page

2130

DOI

10.1021/ja9722077

Abstract

Proton-transfer reactions involving the silaformyl anion, HSiO-, and its conjugate acids, HSiOH and H2SiO, have been investigated with ab initio methods. Calculations through fourth-order perturbation theory suggest possible routes for proton transfer. Accurate estimates for the acidity of H2SiO and HSiOH are presented and discussed in light of earlier experimental estimates.

Comments

Reprinted (adapted) with permission from Journal of the American Chemical Society 120 (1998): 2124, doi:10.1021/ja9722077. Copyright 1998 American Chemical Society.

Copyright Owner

American Chemical Society

Language

en

File Format

application/pdf

Included in

Chemistry Commons

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