Campus Units

Chemistry

Document Type

Article

Publication Version

Published Version

Publication Date

6-2007

Journal or Book Title

Organometallics

Volume

26

Issue

18

First Page

4568

Last Page

4574

DOI

10.1021/om700306x

Abstract

Ab initio methods demonstrate that internally protonated forms (a) of the molecules of carbatranes XC(SiH2CH2CH2)3N (X = H, F) are significantly more favorable than their externally protonated forms (b). The quantum-topological AIM approach suggests that the main reason for that is the formation of a medium-strength hydrogen C···H+N bond unknown previously in the silacarbanyl cations a.

Comments

Reprinted (adapted) with permission from Organometallics 26 (2007): 4568, doi:10.1021/om700306x. Copyright 2007 American Chemical Society.

Copyright Owner

American Chemical Society

Language

en

File Format

application/pdf

Included in

Chemistry Commons

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