Campus Units

Chemistry

Document Type

Article

Publication Version

Published Version

Publication Date

9-1990

Journal or Book Title

The Journal of Organic Chemistry

Volume

55

Issue

20

First Page

5423

Last Page

5424

DOI

10.1021/jo00307a001

Abstract

Summary: The reaction of nucleophiles with bridgehead bromides 3 and 4 affords rearrangement products resulting from addition of the nucleophile to the carbonyl group followed by ring contraction. This rearrangement has been employed in a direct synthesis of epi-modhephene.

Comments

Reprinted (adapted) with permission from The Journal of Organic Chemistry,55(20); 5423-5424. Doi: 10.1021/jo00307a001. Copyright 1990 American Chemical Society.

Copyright Owner

American Chemical Society

Language

en

File Format

application/pdf

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