Campus Units
Chemistry
Document Type
Article
Publication Version
Published Version
Publication Date
6-1991
Journal or Book Title
The Journal of Organic Chemistry
Volume
56
Issue
13
First Page
4147
Last Page
4151
DOI
10.1021/jo00013a014
Abstract
A Synthesis of modhephene has been achieved, the key feature of which is the use of a novel nucleophilic addition/rearrangement reaction to develop the carbon framework. Stereochemical control of the stereogenic center bearing the methyl group was accomplished by variation of the hydrogenation conditions. As a byproduct of this work, we have clarified structural assignments of intermediates from previous syntheses.
Copyright Owner
American Chemical Society
Copyright Date
1991
Language
en
File Format
application/pdf
Recommended Citation
Kraus, George A. and Shi, Jianmin, "Reactions of bridgehead halides. A synthesis of modhephene, isomodhephene, and epi-modhephene" (1991). Chemistry Publications. 616.
https://lib.dr.iastate.edu/chem_pubs/616
Comments
Reprinted (adapted) with permission from The Journal of Organic Chemistry, 56(13); 4147-4151. Doi: 10.1021/jo00013a014. Copyright 1991 American Chemical Society.