Campus Units

Chemistry

Document Type

Article

Publication Version

Published Version

Publication Date

8-1991

Journal or Book Title

The Journal of Organic Chemistry

Volume

56

Issue

17

First Page

5098

Last Page

5100

DOI

10.1021/jo00017a020

Abstract

When quinone 6 was treated with diene I followed by oxidation, a 1,5-dihydroxyanthraquinone was obtained. When quinone 6 was subjected to a palladium-mediated aromatization, the reaulting bhydroxy-l,4naphthoquinone read with diene 7 followed by oxidation to produce a l,&dihydroxyanthraquinone, a key intermediate in a direct synthesis of 7-deoxyaklavinone, a known synthetic precursor of aklavinone.

Comments

Reprinted (adapted) with permission from The Journal of Organic Chemistry, 56(17); 5098-5100. Doi: 10.1021/jo00017a020. Copyright 1991 American Chemical Society.

Copyright Owner

American Chemical Society

Language

en

File Format

application/pdf

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