Organic synthesis using bridgehead carbocations and bridgehead enones
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The Department of Chemistry seeks to provide students with a foundation in the fundamentals and application of chemical theories and processes of the lab. Thus prepared they me pursue careers as teachers, industry supervisors, or research chemists in a variety of domains (governmental, academic, etc).
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The Department of Chemistry was founded in 1880.
Dates of Existence
1880-present
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- College of Liberal Arts and Sciences (parent college)
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Abstract
The development of new pathways by which organic molecules can be stereoselectively constructed remains an important direction for organic chemistry. The palladium-mediated cyclizations of Trost,' Stille? Hegedus,3 Larock," Negishi: and Overman6 and the radical cyclization reactions of Keck,' Stork: Hart: Curran,Io Barton," and Beckwith12 represent important new strategies. A comparatively unstudied strategy is the formation of bicyclic or tricyclic systems via reactive bridgehead intermediates.
Comments
Reprinted (adapted) with permission from Chemical Reviews, 89(7); 1591-1598. Doi: 10.1021/cr00097a013. Copyright 1989 American Chemical Society.