Campus Units

Chemistry

Document Type

Article

Publication Version

Published Version

Publication Date

4-1988

Journal or Book Title

The Journal of Organic Chemistry

Volume

53

Issue

7

First Page

1397

Last Page

1400

DOI

10.1021/jo00242a011

Abstract

The cycloaddition reactions of bridgehead enones derived in situ from ketones 8,9, and 10 with various dienes at 0 "C afford good yields of adducta. Even 1,1,3-trisubstituted dienes work well. The exclusive exo stereochemistry can be rationalized in terms of a stepwise mechanism involving ionic intermediates.

Comments

Reprinted (adapted) with permission from The Journal of Organic Chemistry, 53(7); 1397-1400. Doi: 10.1021/jo00242a011. Copyright 1988 American Chemical Society.

Copyright Owner

American Chemical Society

Language

en

File Format

application/pdf

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