Campus Units

Chemistry

Document Type

Article

Publication Version

Published Version

Publication Date

9-1983

Journal or Book Title

The Journal of Organic Chemistry

Volume

48

Issue

19

First Page

3265

Last Page

3268

DOI

10.1021/jo00167a021

Abstract

Intermediates for the synthesis of olivin and rhodomycinone were prepared by a sequence involving a Diels-Alder reaction followed by a Friedel-Crafts cyclization. In all cases optimal yields were obtained by regioselective methanolysis of anhydrides 9,10, and 21 followed by treatment of the crude ester acids with trifluoroacetic anhydride. An added advantage of the latter reaction is that aromatization also occurs.

Comments

Reprinted (adapted) with permission from The Journal of Organic Chemistry, 48(19); 3265-3268. Doi: 10.1021/jo00167a021. Copyright 1983 American Chemical Society.

Copyright Owner

American Chemical Society

Language

en

File Format

application/pdf

Share

COinS