Synthesis and Characterization of (lmido)titanium(IV) Porphyrin Complexes. X-ray Structure of (Phenylimido )( tetratolylporphyrinato )titanium(IV)
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The Department of Chemistry seeks to provide students with a foundation in the fundamentals and application of chemical theories and processes of the lab. Thus prepared they me pursue careers as teachers, industry supervisors, or research chemists in a variety of domains (governmental, academic, etc).
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The Department of Chemistry was founded in 1880.
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1880-present
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- College of Liberal Arts and Sciences (parent college)
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Abstract
Group 4 metal complexes containing terminal imido ligands have received considerable attention over the past few years. 2- 7 However, metalloporphyrin species containing imido ligands are quite rare and only a small number have been characterized. 8-11 Smieja et al. recently reported the first X-ray crystallographic study of an organoimido metalloporphyrin complex, (TTP)Os(=NC6~-p-N0z)z. 12· 13 We now wish to report a general method for the preparation of the first (organoimido)titanium porphyrin complexes from the reaction of (TIP)TiCh with lithium amides.
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Reprinted (adapted) with permission from Inorganic Chemistry 34 (1995): 527, doi:10.1021/ic00107a001. Copyright 1995 American Chemical Society.