Campus Units

Chemistry

Document Type

Article

Publication Version

Published Version

Publication Date

1-1998

Journal or Book Title

Inorganic Chemistry

Volume

37

Issue

1

First Page

5

Last Page

9

DOI

10.1021/ic970961n

Abstract

Facile syntheses of the meso-tetra-p-tolylporphyrin (TTP) complexes trans-(TTP)Ti(THF)2(1), (TTP)Sn (2), and trans-(TTP)V(THF)2 (3) are achieved through homogeneous reduction of high-valent precursors using NaBEt3H. The composition of the new compound trans-(TTP)Ti(THF)2 was determined by spectroscopic and chemical characterization. Ligand displacement reactions of trans-(TTP)Ti(THF)2 with t-BuNC produced a new Ti(II) complex,trans-(TTP)Ti(t-BuNC)2. The ligand-binding preference of (TTP)TiIILn (n = 1, 2) is picoline ∼pyridine > t-BuNC > PhC⋮CPh > EtC⋮CEt > THF.

Comments

Reprinted (adapted) with permission from Inorganic Chemistry 37 (1998): 5, doi:10.1021/ic970961n. Copyright 1998 American Chemical Society.

Copyright Owner

American Chemical Society

Language

en

File Format

application/pdf

Included in

Chemistry Commons

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