Campus Units
Chemistry
Document Type
Article
Publication Version
Published Version
Publication Date
1-1998
Journal or Book Title
Inorganic Chemistry
Volume
37
Issue
1
First Page
1
Last Page
4
DOI
10.1021/ic970952e
Abstract
Treatment of (TTP)Ti(η2-RC⋮CR) (R = Et or Ph) with PhNNPh results in formation of the azobenzene adduct (TTP)Ti(η2-PhNNPh) (1) in good isolated yield. Complex 1 reacts with (TTP)Ti(η2-RC⋮CR) at elevated temperatures to cleanly afford 2 equiv of the phenylimido compound, (TTP)TiNPh (2). The azobenzene complex, 1, is also formed in low yields by the reaction of the (TTP)TiNPh (2) with excess 1,2-diphenylhydrazine. The electrochemistry of the azobenzene adduct (1) and the phenylimido complex (2) is investigated by cyclic voltammetry experiments.
Copyright Owner
American Chemical Society
Copyright Date
1998
Language
en
File Format
application/pdf
Recommended Citation
Gray, Steven D.; Thorman, Joseph Lyndon; Adamian, Victor A.; Kadish, Karl M.; and Woo, L. Keith, "Synthesis, Electrochemistry, and Imido Transfer Reactions of (TTP)Ti(η2-PhNNPh)" (1998). Chemistry Publications. 766.
https://lib.dr.iastate.edu/chem_pubs/766
Comments
Reprinted (adapted) with permission from Inorganic Chemistry 37 (1998): 1, doi:10.1021/ic970952e. Copyright 1998 American Chemical Society.