Campus Units

Chemistry

Document Type

Article

Publication Version

Published Version

Publication Date

1-1998

Journal or Book Title

Inorganic Chemistry

Volume

37

Issue

1

First Page

1

Last Page

4

DOI

10.1021/ic970952e

Abstract

Treatment of (TTP)Ti(η2-RC⋮CR) (R = Et or Ph) with PhNNPh results in formation of the azobenzene adduct (TTP)Ti(η2-PhNNPh) (1) in good isolated yield. Complex 1 reacts with (TTP)Ti(η2-RC⋮CR) at elevated temperatures to cleanly afford 2 equiv of the phenylimido compound, (TTP)TiNPh (2). The azobenzene complex, 1, is also formed in low yields by the reaction of the (TTP)TiNPh (2) with excess 1,2-diphenylhydrazine. The electrochemistry of the azobenzene adduct (1) and the phenylimido complex (2) is investigated by cyclic voltammetry experiments.

Comments

Reprinted (adapted) with permission from Inorganic Chemistry 37 (1998): 1, doi:10.1021/ic970952e. Copyright 1998 American Chemical Society.

Copyright Owner

American Chemical Society

Language

en

File Format

application/pdf

Included in

Chemistry Commons

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