Campus Units

Chemistry

Document Type

Article

Publication Version

Published Version

Publication Date

1996

Journal or Book Title

Journal of the American Chemical Society

Volume

118

Issue

48

First Page

12238

Last Page

12239

DOI

10.1021/ja962263s

Abstract

Tantalum halide cluster chemistry is dominated by the highly stable octahedral [Ta6X12]n+ clusters (X ) Cl, Br, I) found in reduced binaries with compositions Ta6X14 and Ta6X15 1 and by dinuclear species like TaX4 (also formulated Ta2X6X4/2)2 and the abundant Ta2Cl6L3 complexes and their derivatives.3 Known tantalum chalcogenide halides are limited to one-dimensional compounds of the type (TaQ4)nX (Q ) Se, Te; n ) 1, 2, 4; X ) Br, I)4 and to the structurally uncharacterized solids TaSCl3 and TaS2Cl2.5

Comments

Reprinted (adapted) with permission from J. Am. Chem. Soc., 1996, 118 (48), pp 12238–12239. Copyright 1996 American Chemical Society.

Copyright Owner

American Chemical Society

Language

en

File Format

application/pdf

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