Towards Wireless Characterization of Solvated Ions with Uncoated Resonant Sensors

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2020-01-01
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Carr, Adam
Wu, Jiahao
Beierle, Andee
Thomas, Dustin
Long, Leigh Ann
Soupir, Michelle
Neihart, Nathan
Reuel, Nigel
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Neihart, Nathan
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Soupir, Michelle
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Electrical and Computer Engineering

The Department of Electrical and Computer Engineering (ECpE) contains two focuses. The focus on Electrical Engineering teaches students in the fields of control systems, electromagnetics and non-destructive evaluation, microelectronics, electric power & energy systems, and the like. The Computer Engineering focus teaches in the fields of software systems, embedded systems, networking, information security, computer architecture, etc.

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The Department of Electrical Engineering was formed in 1909 from the division of the Department of Physics and Electrical Engineering. In 1985 its name changed to Department of Electrical Engineering and Computer Engineering. In 1995 it became the Department of Electrical and Computer Engineering.

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Chemical and Biological Engineering

The function of the Department of Chemical and Biological Engineering has been to prepare students for the study and application of chemistry in industry. This focus has included preparation for employment in various industries as well as the development, design, and operation of equipment and processes within industry.Through the CBE Department, Iowa State University is nationally recognized for its initiatives in bioinformatics, biomaterials, bioproducts, metabolic/tissue engineering, multiphase computational fluid dynamics, advanced polymeric materials and nanostructured materials.

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Since 1905, the Department of Agricultural Engineering, now the Department of Agricultural and Biosystems Engineering (ABE), has been a leader in providing engineering solutions to agricultural problems in the United States and the world. The department’s original mission was to mechanize agriculture. That mission has evolved to encompass a global view of the entire food production system–the wise management of natural resources in the production, processing, storage, handling, and use of food fiber and other biological products.

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Abstract

Uncoated resonant sensors are presented here for wireless monitoring of solvated ions, with progress made toward monitoring nitrates in agricultural runoff. The sensor, an open-circuit Archimedean coil, is wirelessly interrogated by a portable vector network analyzer (VNA) that monitors the scattering parameter response to varying ionic concentrations. The sensor response is defined in terms of the resonant frequency and the peak-to-peak amplitude of the transmission scattering parameter profile (|S21|). Potassium chloride (KCl) solutions with concentrations in the range of 100 nM – 4.58 M were tested on nine resonators having different length and pitch sizes to study the effect of sensor geometry on its response to ion concentration. The resonant sensors demonstrated an ion-specific response, caused by the variations in the relative permittivity of the solution, which was also a function of the resonator geometry. A lumped circuit model, which fit the experimental data well, confirms signal transduction via change in solution permittivity. Also, a ternary ionic mixture (composed of potassium nitrate (KNO3), ammonium nitrate (NH4NO3), and ammonium phosphate (NH4H2PO4)) response surface was constructed by testing 21 mixture variations on three different sensor geometries and the phase and magnitude of scattering parameters were monitored. It was determined that the orthogonal responses presented by resonant sensor arrays can be used for quantifying levels of target ions in ternary mixtures. Applications of these arrays include measuring the concentration of key ions in bioreactors, human sweat, and agricultural waters. Preliminary results are shown for calibration standards and real waterway samples in Iowa, USA.

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This is a pre-print of the article Charkhabi, Sadaf, Adam R. Carr, Jiahao Wu, Subhanwit Roy, Andee M. Beierle, Dustin K. Thomas, Leigh Ann M. Long, Michelle Soupir, Nathan M. Neihart, and Nigel F. Reuel. "Towards Wireless Characterization of Solvated Ions with Uncoated Resonant Sensors," ChemRxiv (2020). DOI: 10.26434/chemrxiv.9595628.v2. Posted with permission.

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Wed Jan 01 00:00:00 UTC 2020
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