Degree Type

Dissertation

Date of Award

2016

Degree Name

Doctor of Philosophy

Department

Chemistry

Major

Inorganic Chemistry

First Advisor

Patricia A. Thiel

Abstract

This thesis summarizes research completed on two different model systems. In the first system, we investigate the deposition of the elemental metal dysprosium on highly-oriented pyrolytic graphite (HOPG) and its resulting nucleation and growth. The goal of this research is to better understand the metal-carbon interactions that occur on HOPG and to apply those to an array of other carbon surfaces. This insight may prove beneficial to developing and using new materials for electronic applications, magnetic applications and catalysis.

In the second system, we investigate the intermetallic single crystal NaAu2. We conducted a characterization of the clean (111) surface along with a determination of the effects of gas exposures on the surface. No surfaces of bulk NaAu2 have been previously characterized, although the closely related system of Na films on Au(111) has been investigated. NaAu2 is an active catalyst for CO oxidation. To better understand the catalytic reaction occurring, we studied the NaAu2 surface after exposure to O2,g, COg, CO2,g and H2Og. The goal of this research is to find a possible alternative for supported gold catalysts by utilizing an Au-rich intermetallic compound and to determine how its catalytic reaction proceeds. This insight may be valuable in determining other catalytic alternatives as well as helping understand catalytic reactions that occur with other intermetallic compounds.

In order to characterize and examine these systems, we utilized several ultrahigh vacuum (UHV) techniques, including scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy (XPS) and low-energy electron diffraction (LEED).

Copyright Owner

Emma J. Kwolek

Language

en

File Format

application/pdf

File Size

294 pages

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