Pt-Zn Intermetallic Compounds for Heterogenous Catalysis

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Date
2016-04-27
Authors
Johnston, Sydney
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Honors Projects and Posters
University Honors Program

The Honors project is potentially the most valuable component of an Honors education. Typically Honors students choose to do their projects in their area of study, but some will pick a topic of interest unrelated to their major.

The Honors Program requires that the project be presented at a poster presentation event. Poster presentations are held each semester. Most students present during their senior year, but may do so earlier if their honors project has been completed.

This site presents project descriptions and selected posters for Honors projects completed since the Fall 2015 semester.

Department
Chemical and Biological Engineering
Abstract

Efficient catalysts are a pre-requisite in sustainable energy-driven industries of the future. In the selective hydrogenation of furfural to furfuryl alcohol the industrial catalyst, copper-chromite, is commonly used. However, the process of producing the furfuryl alcohol is inefficient because the catalyst is not sufficiently durable and has to be continually replaced or regenerated. Additionally copper chromite also creates toxic chromium that is harmful to the environment. The research presented here looks at creating nanoscale intermetallic nanoparticles used in the hydrogenation of furfural selectively to furfuryl alcohol when Pt-Zn intermetallic compounds are used. A mesoporous silica shell is used to address the problem of particles aggregating when forming the intermetallic compound. The silica shell has shown no disadvantages in the processes, but further promotes the formation of the intermetallic compound. These results are promising towards the use of intermetallic compounds to promote selectivit...

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