Campus Units

Agricultural and Biosystems Engineering, Chemical and Biological Engineering, Mechanical Engineering, Bioeconomy Institute (BEI)

Document Type

Article

Publication Version

Accepted Manuscript

Publication Date

4-15-2019

Journal or Book Title

Fuel

Volume

242

First Page

837

Last Page

845

DOI

10.1016/j.fuel.2019.01.039

Abstract

This study focuses on the fate of carbon in the char generated by devolatilization of biomass during fluidized bed gasification. A carbon balance model was developed to distinguish between char transformed to carbon-bearing gases and its comminution and elutriation as fine char during gasification. The model accurately predicts the transient accumulation of char carbon in the reactor. Experiments revealed steady state reactor char carbon loadings were achieved after multiple hours of gasification. The model formed the basis of an experimental methodology that assesses the transformation of char carbon based on collection of elutriated solids from the reactor and assessment of the steady state char carbon loading in the reactor. Experiments were performed to distinguish the relative contributions of chemical reaction and physical comminution toward conversion of char to gaseous and solid products. The effects of equivalence ratio, gasification temperature, superficial gas velocity, biomass particle size, and the addition of steam on the partitioning of char carbon between gaseous and solid products during gasification of ground seed corn in a bubbling fluidized bed were investigated. This study revealed that char conversion during gasification of biomass was limited by elutriation of fine char particles arising from fragmentation or attrition of primary char product. Additionally, increased chemical reaction of char to form gases was usually accompanied by increased elutriation of fine char, which suggests that chemical reaction increased the porosity of the char and its susceptibility to fragmentation and attrition. Finally, decreasing superficial gas velocity, increasing equivalence ratio, and decreasing particle size led to increased carbon conversion, while increasing temperature and steam concentration in the reactor had negligible effect.

Comments

This is a manuscript of an article published as Timmer, Kevin J. and Robert C. Brown. "Transformation of char carbon during bubbling fluidized bed gasification of biomass." Fuel 242 (2019): 837-845. DOI: 10.1016/j.fuel.2019.01.039. Posted with permission.

Creative Commons License

Creative Commons Attribution-Noncommercial-No Derivative Works 4.0 License
This work is licensed under a Creative Commons Attribution-Noncommercial-No Derivative Works 4.0 License.

Copyright Owner

Elsevier Ltd.

Language

en

File Format

application/pdf

Available for download on Friday, January 01, 2021

Published Version

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